Synthesis and Characterization of Novel Basketing of C-4-Phenylocta Phenylhydrazide-Calix[4]Resorcinarene Pdnps

Abstract

The novel synthesis basketing of C-4-phenylocta(phenylhydrazide)calix[4]resorcinarene-PdNPs/(K4ROPH-PdNPs).The route have been synthesized target compounds, including: (1) C-4-phenyloctahydroxycalix[4]resorcinarene,(K4R), (2)C-4-phenyloctahydroxycalix[4]resorcinarene-acetate, (3) C-4-phenyloctaphenylhydrazidecalix[4]resorcinarene-amida(K4ROPH) and (4) C-4-phenylocta(phenylhydrazide)calix[4]resorcinarene-PdNPs. (K4ROPH-NPs). Compounds of K4ROPH-PdNPs were characterized carried out with FTTR, TEM, 1H-NMR (500 MHz, DMSO-d6), and UV-Vis to determine ligands functional groups and particle size of ligands before and after being complexed with palladium transition metals. The results of particle size analysis using Transmission Electron Microscopy (TEM), obtained of K4ROPH-PdNPs have a particle size between 3-13 nm.